Voltammetric Determination of Lead at Chemically Modified Electrodes Based on Crown Ethers.
نویسندگان
چکیده
منابع مشابه
Voltammetric determination of copper at chemically modified electrodes based on crown ethers.
The feasibility of fabricating copper-sensitive chemically modified electrodes (CMEs) for trace analysis in aqueous and in 40% (v/v) ethanol-water media was investigated. Carbon paste electrodes modified with crown ethers were constructed by mixing the crown ethers into a graphite powder-paraffin oil matrix. The electrodes so formed were able to bind Cu(II) ions chemically and gave better volta...
متن کاملSimultaneous voltammetric determination of heavy metals by use of crown ether-modified electrodes and chemometrics
A three-sensor array consisting of a graphite-epoxy composite electrode (GEC), 4-carboxybenzo-18-crown-6-GEC and 4carboxybenzo-15-crown-5-GEC was employed for the simultaneous determination of Cd(II), Pb(II) and Hg(II) by differential pulse anodic stripping voltammetry (DPASV). Sensors were firstly studied for the determination of Hg(II); secondly, peak current responses confirmed that all sens...
متن کاملVoltammetric determination of trace mercury in chloride media at glassy carbon electrodes modified with polycationic ionomers
The perfluorinated polycationic polymer Tosflex @ is used for preparing polymer modified electrodes able to preconcentrate and detect the anionic complex HgCl$-, which is the prevailing inorganic Hg(II) species in sea water and other chloride media. The study of the ion-exchange voltammetric behaviour of the tetrachloromercurate(I1) complex at Tosflex-modified electrodes indicates the efficient...
متن کاملModelling Amperometric Biosensors Based on Chemically Modified Electrodes
The response of an amperometric biosensor based on a chemically modified electrode was modelled numerically. A mathematical model of the biosensor is based on a system of non-linear reaction-diffusion equations. The modelling biosensor comprises two compartments: an enzyme layer and an outer diffusion layer. In order to define the main governing parameters the corresponding dimensionless mathem...
متن کاملVoltammetric determination of amitriptyline based on graphite screen printed electrode modified with a Copper Oxide nanoparticles
A novel electrochemical sensor was proposed for the determination of amitriptyline based on the copper oxide (CuO) nanoparticles modified graphite screen-printed electrode. CuO nanoparticles were used to enhance the surface area of the electrode and then improve the sensitivity of the electrochemical sensor. Amitriptyline electrochemical response characteristics of the modified electrode in a p...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Analytical Sciences
سال: 2001
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.17.605